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Boyle's Law
P₁V₁ = P₂V₂ (T constant)
Pressure and volume are inversely proportional at constant temperature.
Charles's Law
V₁/T₁ = V₂/T₂ (P constant)
Volume and temperature are directly proportional at constant pressure.
Gay-Lussac's Law
P₁/T₁ = P₂/T₂ (V constant)
Pressure and temperature are directly proportional at constant volume.
Combined Gas Law
P₁V₁/T₁ = P₂V₂/T₂
Combines Boyle's, Charles's, and Gay-Lussac's laws.
Ideal Gas Law
PV = nRT
Relates pressure, volume, temperature, and moles of gas.
Question 1
Correct!
Solution:
Gas Law Basics
Key Gas Laws
| Law | Equation | Relationship | Constant Parameter |
|---|---|---|---|
| Boyle's Law | P₁V₁ = P₂V₂ | Pressure and volume are inversely proportional | Temperature |
| Charles's Law | V₁/T₁ = V₂/T₂ | Volume and temperature are directly proportional | Pressure |
| Gay-Lussac's Law | P₁/T₁ = P₂/T₂ | Pressure and temperature are directly proportional | Volume |
| Combined Gas Law | P₁V₁/T₁ = P₂V₂/T₂ | Combines all three simple gas laws | Amount of gas (moles) |
| Ideal Gas Law | PV = nRT | Relates all four gas variables | Gas constant (R) |
Constants
- R (Ideal Gas Constant): 0.0821 L·atm/mol·K
- Standard Temperature and Pressure (STP): 0°C (273.15 K) and 1 atm
- Molar Volume at STP: 22.4 L/mol
Sample Problems
Problem: A gas occupies 2.0 L at 1.0 atm. What will be its volume at 2.0 atm (constant temperature)?
Solution:
Using Boyle's Law: P₁V₁ = P₂V₂
(1.0 atm)(2.0 L) = (2.0 atm)(V₂)
V₂ = (1.0 × 2.0) / 2.0 = 1.0 L
Problem: A gas occupies 3.0 L at 273 K. What will be its volume at 546 K (constant pressure)?
Solution:
Using Charles's Law: V₁/T₁ = V₂/T₂
3.0 L / 273 K = V₂ / 546 K
V₂ = (3.0 × 546) / 273 = 6.0 L
Problem: Calculate the pressure exerted by 1.0 mol of gas in a 22.4 L container at 273 K.
Solution:
Using Ideal Gas Law: PV = nRT
P = nRT/V = (1.0 mol)(0.0821 L·atm/mol·K)(273 K) / 22.4 L
P = 1.0 atm
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