What is Charles's Law?
Charles's Law (also known as the law of volumes) describes how gases tend to expand when heated. It states that:
The volume of a given amount of gas is directly proportional to its temperature on the Kelvin scale when the pressure is held constant.
Mathematically, this can be expressed as:
V₁/T₁ = V₂/T₂
where:
- V₁ = Initial volume
- T₁ = Initial temperature (in Kelvin)
- V₂ = Final volume
- T₂ = Final temperature (in Kelvin)
Key Points:
- The law applies only to ideal gases (real gases approximate this behavior at high temperatures and low pressures).
- Temperature must be measured in Kelvin for the law to hold true.
- The pressure and amount of gas must remain constant for the relationship to be valid.
- Charles's Law is one of the gas laws that form the combined gas law and ultimately the ideal gas law.
Historical Context:
Charles's Law was first published by French natural philosopher Joseph Louis Gay-Lussac in 1802, but he credited the discovery to unpublished work from the 1780s by Jacques Charles. The law was independently discovered by British natural philosopher John Dalton in 1801.