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Vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. It's an important property in thermodynamics and physical chemistry that indicates a substance's evaporation rate.
When the vapor pressure equals the external pressure, the liquid boils. Substances with higher vapor pressures at normal temperatures are considered more volatile. Understanding this concept is essential when working with related metrics like various pressure units or exploring the behavior of gases.
Common units for vapor pressure include:
For broader pressure conversions beyond vapor pressure, you might find our online pressure converter and atmospheric pressure converter helpful for your calculations.
The Antoine equation is a semi-empirical relationship between vapor pressure and temperature for pure substances:
log₁₀(P) = A - B/(C + T)
Where:
The equation is accurate for a limited temperature range and different sets of coefficients may be needed for different temperature ranges. For conversions involving thermal properties, you may also explore our thermal conductivity converter.
Unit Conversion:
Temperature Calculation:
Use the precision selector to control decimal places and toggle scientific notation as needed.
What your numbers mean:
| Use This Unit... | When Working With... | Example |
|---|---|---|
| mmHg / Torr | Chemistry labs, medicine (blood pressure), vacuum systems | Measuring vapor pressure of solvents |
| atm | General chemistry problems, atmospheric science | "Express in atmospheres" textbook questions |
| kPa / Pa | Physics problems, engineering calculations (SI system) | International research papers |
| psi | Mechanical engineering, industrial applications (US) | Pressure cooker settings, tire pressure |
| bar / mbar | Meteorology, European engineering, automotive | Weather maps (millibars) |
Water boils at 100°C at 1 atm (760 mmHg). At higher altitudes with lower pressure, water boils at lower temperatures.
High pressure systems (∼1020 mbar) bring clear weather. Low pressure (∼980 mbar) often means storms. For accurate measurements, try our atmospheric pressure converter.
Normal blood pressure is ∼120/80 mmHg. Vacuum tubes use ∼0.1 mmHg for blood collection.
Q: Why are Torr and mmHg treated as equal?
A: They were defined to be essentially identical (1 Torr = 1/760 atm, 1 mmHg = 1/760 atm). For most practical purposes, they're interchangeable.
Q: What's the difference between absolute and gauge pressure?
A: Absolute pressure includes atmospheric pressure. Gauge pressure is relative to atmosphere. PSI vs PSIA: PSI is usually gauge, PSIA is absolute.
Q: Why does vapor pressure increase with temperature?
A: More molecules have enough energy to escape the liquid. Double the temperature (in Kelvin) doesn't double vapor pressure - it increases exponentially! Our pressure-temperature converter can help illustrate this relationship.
Q: Can vapor pressure be higher than atmospheric pressure?
A: Yes! This is how pressure cookers work. At 121°C, water's vapor pressure is about 2 atm.
For Educational Use: This tool provides accurate conversions for standard conditions. Actual vapor pressures can vary with purity, altitude, and other factors.
Antoine Equation Limits: The Antoine coefficients are valid for specific temperature ranges. Extreme temperatures may require different coefficient sets.
Rounding: 4 decimal places is usually sufficient for classroom work. For precise engineering, consult specialized references.
Last Updated: November 2025 | Conversion formulas verified against NIST standards.
Learning Tip: Practice by converting everyday pressures: car tires (∼32 psi), weather reports (∼1013 mbar), and soda cans (∼4 atm CO₂ pressure).